The high pressure sensor is found on the right side, around the middle, of the condenser coil. I've attached a picture, it's #7 in the picture.
Are you sure the sensor is bad? The code doesn't necessarily mean a bad sensor. DTC indicates the sensor is tripped due to not meeting minimal pressure on the high side. If you have a scan tool like VCDS try to see if you can read the sensor and see if it's showing any pressure. If the sensor is giving data then it's probably not bad. If that's the case then you have a leak somewhere which will require tracing with a sniffer tool and/or uv reactive dye.
If you're not familiar it's best to have someone else perform the work at this point. Don't mess with those AutoZone refill kits, they're garbage. If you do wanna try your luck at just topping it up and seeing how long it lasts (it went somewhere) at least get a decent set of gauges from amazon and a few cans of refrigerant with dye to go with it, that way you can properly fill the system to capacity and not over/under like with the AutoZone junk. VW does not approve the use of stop leak chemicals, nor have I found those useful myself. Capacities are 590 grams for R134a and 525 grams for R1234yf, depending on which your car has (early 2018 MY had R1234yf).
You can also throw some gauges on and see if the pressure is good with the AC running, which would point to bad sensor. If you do find that it's the sensor, you need to take the top cover above the front fascia off, not sure if the fascia has to come off or not, but on RS grille I believe you can keep the fascia on for sure. It does say to replace the o-ring and coat it with refrigerant oil. Also if refrigerant flows for more than a second when you loosen the sensor, tighten it back up, it means the upstream check valve is broken and will need to be replaced as it's going to dump out your refrigerant.
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