Check for timing chain rattle on cold start. If you hear a loud-ish rattle that lasts 3 seconds or more then I'd avoid. It's very uncommon but it does occasionally happen so good to be aware of.
Aside from that, you can expect to do some serious maintenance just about immediately when you get it. Namely, the transmission fluid and filter will need to be changed if the previous owner never did it. Recommended change interval is 60k miles or so if I remember.
Less important but also likely, is intake valve carbon cleaning. At 100k miles mine were pretty gunked and GROSS. By 150k I'd there may be power loss or rougher idle that you would probably notice if you compare to a low mileage 3.0T. If you do this maintenance, it's also recommended to replace the PCV, thermostat, and water pump at the same time as they are failure prone and easy to access while the supercharger is off for intake valve cleaning.
If you do all these tasks yourself, expect the parts cost to be around $800, with about 40hrs in labor for everything above mentioned. Not including special tools or supplies.
Other users here may give more accurate estimates on price and labor times but that's what I roughly spent when I did this myself.
If you feel up to the task, the 3.0T paired with the 8 speed ZF8 transmission is among the most reliable platforms in the Audi lineup. Assuming maintenance is all up to date and no timing chain issues, this car would easily get up to 200k.
Good luck in your search.
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