Yeah I sort of see what you are saying, certainly 65 with A/C on is not the same as 65 with A/C off. You'd think they should be but they are not.
70-72 with A/C on seems to be about right. I can't say it is "uncomfortably" warm as you mention with A/C off, but it does usually drive the fan harder to try to maintain the set temp without A/C on and if it is above 65 outside it really cannot do it.
The only suggestions I have are:
Cycle through all the vent distribution adjustments I've heard of some getting stuck and then perhaps it could be as you said it is passing through the heater core when it should not be.
Check footwell temperature setting...I know it sounds dumb as that "should" only effect the footwell, but again stuck vent distribution damper somewhere may affect things differently.
Check coolant mix. If it is not 50% or max 55% per spec it could potential affect things like heating and cooling, both interior and engine.
Audi tool to check coolant T10007A or B now but you can find cheaper version on Amazon
https://erwin.seat.com/workshop/en/f...0007b_1817.htm
They all seem to be the same made by ATC.
https://www.amazon.com/s?k=coolant+r...f=nb_sb_noss_2
Also for reference these should be the cabin HVAC sensors. (Excluding outside air temp & A/C pressure/temp)
(Just a quick parts lookup, don't have em all and as always check the p/n yourself if you plan to replace any.)
G238 air quality with humidity sensor. In the fresh air intake under the windshield cowl.
G150 Left vent sensor. Up under the driver's dash panel. 3D0907543A
G151 Right vent sensor. Behind the glove box. 3D0907543A
G261 Left footwell vent. Under driver's side panel
G262 Right footwell vent. Behind glove box.
G637/G638 Rear footwell vent. Under the front seats. 4B0820539
G635/G636 Rear upper body vent. Under the center console (Rear center 3D0907543A?)
G623 Evaporator vent sensor. Behind passenger's side footwell vent behind glove box. (4H0907543?)
G107 Sunlight photo sensor. Center dash near windshield.
AFAIK the sensor in the HVAC controls is not a separate part and is only a part of that whole panel.
But as you said any one of them if truly faulty should generate a DTC. However when my outside temp sensor failed on my SQ5 it did not set a DTC since it is just a simple thermistor. I'm sure you could find them all in VCDS and just check to see the temperatures register what you expect and one is not wildly off maybe.
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