I don't think I could make up a "DIY" for it as I didn't keep very careful notes, but the general idea is "keep removing stuff from the top of the engine until you can get to the PCV assembly, replace it, then put all the stuff back". ;^)
I think the thing that might generate the most questions is which lower intake mainfold(s) you need to remove to get the PCV out. The service manual says you only need to remove the left one (viewed from the front of the car) but when I got to that point I realized I had so much stuff off I might as well take the right one off also and clean the carbon off the valves. Oh and I've heard tales from exotic foreign lands of people removing intake manifolds from the engine and having the injectors stay in the head(s), but between my (B8) A4 and this car I've had 10 out of 10 injectors come out with the fuel fail, necessitating changing the seals on said injectors. I worried a lot about a tool kit to change the seals, as I had bought the one from ECS that's intended to work on my (4-cylinder) A4 but they don't say it will work for the 3.0t, and very few people seem to sell kits that work with the 3.0 engine. The face of the little "cone" tool to expand the seal didn't mate to the front of the injectors perfectly, but it was the right size and ultimately the tool did work with little difficulty.
What I replaced? The "reason" for the project was to replace the supercharger pulley with a smaller one (which I know can be done on the car but taking the SC off provided an excuse to do the other stuff). I also replaced the thermostat, water pump (which you don't need the SC off to do but it does make it easier), serpentine belt idler pulley, both serpentine belts (accessory and supercharger), the plastic coolant line running from the thermostat housing to the hose going to the heater core in the back, the crankcase vent tube that connects the PCV assembly to the valve covers, and the PCV assembly.
I changed the coolant since it needed to be drained anyway, and even though the system was drained, it did appear a little coolant got into the crankcase as a result of removing the PCV unit. So being "better safe than sorry" I changed the oil.
Interestingly, although I wasn't aware of it, the water pump did have a problem. The pump actually has a clutch in it that's vacuum-actuated. Although I was going to replace it anyway, before I pulled it off I put a vacuum tester on the line feeding the clutch and it would not hold vacuum. With the pump replaced, the car actually seems to warm up faster.
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