Nothing wrong with reanimating a zombie, sometimes there's good stuff in there that can help people out...
Anyway, I had this same question, and possibly due to my location and proximity to particular sources of fuel, came to my current route after doing a lot of searching. I live within 10 minutes of an E85 and R15 combo pump, as well as have a Sunoco station that sells 100 Octane 260 GT at the pump ($9.99/gal!!!) I am tuned DS1 Stage 4, with all sorts of mechanical mods backing it up, so the car likes octane and ethanol. There is a Sunoco Racing Fuels distributor,
PSC that has almost every offering from Sunoco. They offer local pickup, so I could borrow a van or truck with a ramp, drive an hour, pick up for free and be on my way. Also offer flat rate shipping by weight class, and I think you can get like three 54 gal drums in a shipment before the rate increases, although it is a bit higher to get a lift gate. I am about to order 2 or 3 drums of 260 GT+ (104 octane) and a transfer pump to make my own custom ethanol blends.
I've been mixing at the pump, and watching the ethanol content sensor immediately after refueling, and it seems to adjust and even out after 2-3 miles of driving, and I make sure to jostle the car a bit to shake up the tank. If you're not concerned about ethanol blending, I'd say the same process applies to octane blending. There are good calculators online to put in the quantity and octane of your fuels, and it spits out the total octane of the mix.
I called around to other suppliers, and nobody can beat PSCs prices or shipping, especially with that flat rate option. As for which octane rating to use, use whatever your local fuel is measured in. I am in the US, (as I assume you are) so everything is R+M/2, as are the Sunoco fuels listed on PSCs site, so to make sure you're getting an accurate number, always use the same standard when calculating the average octane of a mix. Most places in the EU use the RON, which is why it looks like they have higher octane fuel, but it's just a different number for the same stuff.
One thing to look out for, and I have talked to others about blending fuels before about, is that you really want to try and stay away from mixing high grade racing fuels with low grade pump gas, ex. 260 GT+ with 87 octane pump gas. Reason being, each will have completely different additives and potentially different densities, along with other characteristics that could result in a less-than-complete blend when you do mix them. Obviously what applies to 87 applies to 93 to some extent, but the closer you are to the race gas octane, the better. I also try and keep it the same brand, again with the additives, so I mix Sunoco with Sunoco, but that may be overkill.
Either way, there is no reason you can't make your own blends, and a good way to tell if it's blending completely would be to take a glass container and mix them in the ratio that you plan to put into the car, let it sit overnight to simulate sitting in the tank in your garage or driveway, and check to see if there is any stratification or other signs that it may not be completely blended.
Sorry for the long post, but I wanted to share my experience with doing this, and let people know about PSC, as I haven't been able to find anyone else that has their selection, prices or shipping rates.
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