Materials needed:
(1) 30-40A single-pole single-throw (SPST) relay
(3) 12-14ga insulated female quick disconnect terminals
(1) 18-22ga insulated female quick disconnect terminal
(1) 12-14ga insulated butt connector
~6" of 12/14ga insulated stranded wire (non-black casing preferable)
~3' of 18-22ga insulated stranded wire (black casing preferable)
Tools needed:
- wire strippers
- pliers
- goo gone
Summary: Power to the rear defroster comes from fuse 26 and into the HVAC on wire F-5. Power goes from the HVAC to the rear defroster via wire F-6. We will re-wire such that F-5 provides constant power to the relay; F-6 will be split to trigger the relay and provide power to the rear defroster.
The DIY:
1) use painters tape to protect ashtray cover and sides of center console near HVAC unit. Remove radio. Remove HVAC.
2) remove 3-4" of the cloth tape from the wires on the 'F' plug, which is located on the far right (of the HVAC unit) and has 2 ~12ga wires going into it. Clean evil residue with goo gone.
F-plug:

cloth tape stripped:

3) cut both wires from the F-plug ~1.5" from the plug. Attach quick disconnect terminals to harness side of bare wires.
4) attach butt connector to wire F-6 (white/lilac) on F-plug; F-5 is unused. attach ~6" of 12-14ga wire to butt connector. Attach quick disconnect terminal to end of extension wire.
5) remove fuse panel access cover and driver side knee bolster. Run 18-22ga ground wire from HVAC area to convenient ground post. attach quick disconnect terminal to HVAC end, trim to length.
6) wire up relay:
F-5 (white/yellow) harness-side to terminal 30
F-6 (white/lilac) harness-side to terminal 87
F-6 from HVAC (extended) to terminal 86
ground wire to terminal 85

7) reconnect HVAC plugs, push relay back/down into chasm below HVAC so it's not in the way. Test HVAC before fully reinstalling.
8) Reinstall HVAC. Reinstall radio. clean up work area.
9) profit :)

edit: found this nice diagram from woorlord on audi-sport.net:

Hope this is useful.
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