Was driving home this past Thursday, had the AC going and went to step on it to get a guy off my back, and the car went into limp mode. Got her over to the side of the road, and couldn't get her to start and idle. Checked the CEL, and got coolant temp. sensor (p2181) and cyl. 2 misfire. Pulled the plugs, they looked alright, and the temp. sensor has been on for a while - assuming thermostat stuck open, haven't gotten to replace it.
Long story short, got AAA to drag me home (it was less than half a mile to my house, ironically). My dad comes over and we take a look, and he's getting the same thing I was.
Car will turn over, and reach maximum of 2k RPM, but will not idle or move forward. We pop the hood, and find that the serpentine belt (intact), is off track. I really don't have any more information than that, but I am curious if there is potential for this to have been something popping the belt off track, or if it's a symptom of something more serious. I want to have some idea before I call my shop to have her towed over.
Car has 140k currently - had my timing belt replaced approx. 25k ago, and my serpentine belt was said to be in good condition, so it was left in. It still seems to be intact, but will be replaced anyway.
Any ideas? Pic for clicks:

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