Just please be careful using such things. Both are very potent known carcinogens. Working in the remediation industry has put me a little on the worry wart side of the fence when it comes to such things, but I figured it bears mentioning. If you want more info, check out the NIOSH (the OSHA is more lenient for various monetary-related reasons while NIOSH cares a lot more about your health).
Just wondering, why would you want 98 (R+M)/2 for your S? I assume you would only add it up to 93 or 95 or so. I have zero issues at 93. Also other VOA's should also be effective in increasing resistance to knock, such as benzenes, MTBE, etc, though toluene and xylene are probably the most available at hardware stores. VOA's are already used as sparingly as possible by refiners due to their potent toxicity, as I said, so use at your own risk.
When looking at that chart, please bear in mind that gasoline isn't the layman's term for the chemical known as octane. Gasoline contains octane, but it also contains many, many other compounds, with no single compound being the main constituent. So looking at a chart that says "octane" and lists chemical properties can be misleading if you think that those properties equal the properties of gasoline.
And finally, as a personal pet peeve, why do some insist on calling 2,2,4-trimethylpentane "octane"? It's not octane; it's an isomer. Grrrrrrrr.
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