Thanks for the updated information. Based on the latest results, I think the #1 injector is faulty. Besides the electrical properties, the mechanical parts of the spray nozzle can malfunction independently from the electrical function. I recommend swapping #1 injector with any one of the other three, then run the engine and determine if the misfiring cylinder follows the #1 injector to the new cylinder location. You will need to replace the #1 injector after confirming the misfires move with the injector swap, to the new cylinder.
The reason #1 cylinder is firing at cold start up, then develops misfires after a few minutes of warm up, is most likely due to the ECU increasing the injector drive pulse width when rich cold start and warm up air/fuel mixtures are are required, then after a few miniutes warm up, the ECU reduces the injector pulse width to lean the air/fuel mixture for warm engine operation.
Since the injector mechanical nozzle parts are not spraying enough fuel, or the fuel spray is very distorted, due to a nozzle defect, there is not enough fuel for the mass air flow into the cylinder, after a couple of minutes of warm up, the resulting air/fuel mixture is to lean to support combustion, thus the misfires with the engine warmed up. The injector is spraying fuel, but not enough for a correct air/fuel mixture, so the air/fuel charge in the cylinder does not ignite, and raw fuel is pumped through cylinder #1 causing the unburned fuel smell.
The ECU OBD II engine monitors do not evaluate the injector mechanical function, so there is no DTC for faulty spray nozzles.
If this was my problem, I am confident enough about the cause of the misfires to skip the injector swap test, and replace the faulty #1 injector with a known good used injector. But you can decide what to do first.
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